α-Formylation of α-substituted ketones

Hassan, Jamal and Richards, Christopher J. ORCID: https://orcid.org/0000-0001-7899-4082 (2012) α-Formylation of α-substituted ketones. Synlett, 2012 (02). pp. 239-242. ISSN 0936-5214

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Abstract

The reaction of (chloromethylene)dimethylammonium chloride (generated in situ from oxalyl chloride and DMF) with α-substituted ketones in CH2Cl2, followed by workup with aqueous NaHCO3, gave β-keto aldehydes containing an α-quaternary centre (8-88% yield).

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis (former - to 2025)
Depositing User:	Users 2731 not found.
Date Deposited:	13 Mar 2012 16:09
Last Modified:	18 Jun 2026 14:41
URI:	https://ueaeprints.uea.ac.uk/id/eprint/38200
DOI:	10.1055/s-0031-1290121

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