An investigation into the diastereoselective palladation of oxazoline appended cobalt metallocenes

Yeamine, Mehbuba R. and Richards, Christopher J. (2007) An investigation into the diastereoselective palladation of oxazoline appended cobalt metallocenes. Tetrahedron: Asymmetry, 18 (22). pp. 2613-2616. ISSN 0957-4166

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Abstract

The diastereoselective reactions of palladium acetate with (eta(5)-(S)-2-(4-methylethyl)oxzazolinylcyclopentadienyl)(eta(4)-tetraph enylcyclobutadiene)cobalt, which gives a planar chiral palladacycle with (R-p) configuration, and (eta(5)-(S)-2-(4-dimethylethyl)oxzazolinylcyclopentadienyl)(eta(4)-tetra phenylcyclobtttadiene)cobalt, which results in the opposite (S-p) configuration, are shown to be a consequence of these reactions displaying thermodynamic and kinetic control, respectively. (c) 2007 Elsevier Ltd. All rights reserved.

Item Type:	Article
Additional Information:	Yeamine, Mehbuba R. Richards, Christopher J.
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	21 Feb 2012 10:39
Last Modified:	28 Mar 2025 03:55
URI:	https://ueaeprints.uea.ac.uk/id/eprint/37281
DOI:	10.1016/j.tetasy.2007.10.028

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