Yeamine, Mehbuba R. and Richards, Christopher J. ORCID: https://orcid.org/0000-0001-7899-4082
(2007)
An investigation into the diastereoselective palladation of oxazoline appended cobalt metallocenes.
Tetrahedron: Asymmetry, 18 (22).
pp. 2613-2616.
ISSN 0957-4166
Abstract
The diastereoselective reactions of palladium acetate with (eta(5)-(S)-2-(4-methylethyl)oxzazolinylcyclopentadienyl)(eta(4)-tetraph enylcyclobutadiene)cobalt, which gives a planar chiral palladacycle with (R-p) configuration, and (eta(5)-(S)-2-(4-dimethylethyl)oxzazolinylcyclopentadienyl)(eta(4)-tetra phenylcyclobtttadiene)cobalt, which results in the opposite (S-p) configuration, are shown to be a consequence of these reactions displaying thermodynamic and kinetic control, respectively. (c) 2007 Elsevier Ltd. All rights reserved.
Item Type: | Article |
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Additional Information: | Yeamine, Mehbuba R. Richards, Christopher J. |
Faculty \ School: | Faculty of Science > School of Chemistry |
Depositing User: | Rachel Smith |
Date Deposited: | 21 Feb 2012 10:39 |
Last Modified: | 24 Oct 2022 01:35 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/37281 |
DOI: | 10.1016/j.tetasy.2007.10.028 |
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