Enantioselective Total Synthesis of (+)-Scuteflorin A Using Organocatalytic Asymmetric Epoxidation

Bartlett, Christopher J., Day, David P., Chan, Yohan, Allin, Steven M., McKenzie, Michael J., Slawin, Alexandra M. Z. and Bulman Page, Philip C. (2012) Enantioselective Total Synthesis of (+)-Scuteflorin A Using Organocatalytic Asymmetric Epoxidation. The Journal of Organic Chemistry, 77 (1). pp. 772-774.

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Abstract

We report the first enantioselective total synthesis of (+)-scuteflorin A in 14% overall yield, employing a chiral iminium salt to effect an organocatalytic asymmetric epoxidation of xanthyletin in >99% ee as the key step.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 16 Feb 2012 11:18
Last Modified: 21 Apr 2020 16:17
URI: https://ueaeprints.uea.ac.uk/id/eprint/37146
DOI: 10.1021/jo2021407

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