Palladacycles as precatalysts in Heck and cross-coupling reactions

Munoz-Herranz, Maria ORCID:, Martín-Matute, Belén, Fernández-Rivas, Carolina, Cárdenas, Diego J. and Echavarren, Antonio M. (2001) Palladacycles as precatalysts in Heck and cross-coupling reactions. Advanced Synthesis & Catalysis, 343 (4). pp. 338-342. ISSN 1615-4150

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A variety of palladacycles are shown to catalyze Heck alkenylations with similar efficiencies. The new oxapalladacycle 1 was shown to insert and transmetalate under mild conditions with n-butyl acrylate and vinyltributylstannane, respectively. This palladacycle acts as an active (pre)catalyst for cross-coupling and Heck reactions.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 14 Feb 2012 16:06
Last Modified: 15 Dec 2022 01:50
DOI: 10.1002/1615-4169(20010226)343:4<338::AID-ADSC338>3.0.CO;2-I

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