Cryptocatalytic 1,2-Alkene Migration in a σ-Alkyl Palladium Diene Complex

Evans, Louise A., Fey, Natalie, Lloyd-Jones, Guy C., Munoz-Herranz, Maria and Slatford, Paul A. (2009) Cryptocatalytic 1,2-Alkene Migration in a σ-Alkyl Palladium Diene Complex. Angewandte Chemie International Edition, 48 (34). pp. 6262-6265. ISSN 1433-7851

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Abstract

Not so simple : A combination of 2H, 13C, and 108Pd labels shows that the alkene migration in a s-alkyl palladium diene complex induced by trifluoromethanesulfonic acid is not intramolecular or acid-mediated, but instead requires a self-generated palladium hydride species (see scheme; Tf=triflate).

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Related URLs:
Depositing User: Rachel Smith
Date Deposited: 14 Feb 2012 16:36
Last Modified: 21 Apr 2020 17:36
URI: https://ueaeprints.uea.ac.uk/id/eprint/37104
DOI: 10.1002/anie.200901468

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