Cryptocatalytic 1,2-alkene migration in a σ-alkyl palladium diene complex

Evans, Louise A., Fey, Natalie, Lloyd-Jones, Guy C., Munoz-Herranz, Maria ORCID: https://orcid.org/0000-0001-9037-349X and Slatford, Paul A. (2009) Cryptocatalytic 1,2-alkene migration in a σ-alkyl palladium diene complex. Angewandte Chemie International Edition, 48 (34). pp. 6262-6265. ISSN 1433-7851

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Abstract

Not so simple : A combination of 2H, 13C, and 108Pd labels shows that the alkene migration in a s-alkyl palladium diene complex induced by trifluoromethanesulfonic acid is not intramolecular or acid-mediated, but instead requires a self-generated palladium hydride species (see scheme; Tf=triflate).

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
Depositing User:	Rachel Smith
Date Deposited:	14 Feb 2012 16:36
Last Modified:	06 Jan 2023 10:32
URI:	https://ueaeprints.uea.ac.uk/id/eprint/37104
DOI:	10.1002/anie.200901468

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