High surface area contorted conjugated microporous polymers based on spiro-bipropylenedioxythiophene

Jiang, Jia-Xing, Laybourn, Andrea, Clowes, Rob, Khimyak, Yaroslav Z., Bacsa, John, Higgins, Simon J., Adams, Dave J. and Cooper, Andrew I. (2010) High surface area contorted conjugated microporous polymers based on spiro-bipropylenedioxythiophene. Macromolecules, 43 (18). pp. 7577-7582. ISSN 0024-9297

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Abstract

Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(2,5-dibromopropylenedioxythiophene) with one of three di- or triethynyl monomers. These polymers have surface areas up to 1631 m2/g and exhibit significant microporosity, suggesting possible applications in the fields of organic electronics or optoelectronics.

Item Type:	Article
Uncontrolled Keywords:	sdg 7 - affordable and clean energy ,/dk/atira/pure/sustainabledevelopmentgoals/affordable_and_clean_energy
Faculty \ School:	Faculty of Science > School of Pharmacy (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Pharmaceutical Materials and Soft Matter Faculty of Science > Research Groups > Drug Delivery and Pharmaceutical Materials (former - to 2017)
Depositing User:	Rhiannon Harvey
Date Deposited:	31 Jan 2012 10:58
Last Modified:	28 Mar 2025 03:05
URI:	https://ueaeprints.uea.ac.uk/id/eprint/36605
DOI:	10.1021/ma101468r

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