High Surface Area Contorted Conjugated Microporous Polymers Based on Spiro-Bipropylenedioxythiophene

Jiang, J-X, Laybourn, A, Clowes, R, Khimyak, YZ, Bacsa, J, Higgins, SJ, Adams, DJ and Cooper, AI (2010) High Surface Area Contorted Conjugated Microporous Polymers Based on Spiro-Bipropylenedioxythiophene. Macromolecules, 43 (18). pp. 7577-7582. ISSN 0024-9297

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Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(2,5-dibromopropylenedioxythiophene) with one of three di- or triethynyl monomers. These polymers have surface areas up to 1631 m2/g and exhibit significant microporosity, suggesting possible applications in the fields of organic electronics or optoelectronics.

Item Type: Article
Faculty \ School: Faculty of Science > School of Pharmacy
Related URLs:
Depositing User: Rhiannon Harvey
Date Deposited: 31 Jan 2012 10:58
Last Modified: 21 Apr 2020 17:13
URI: https://ueaeprints.uea.ac.uk/id/eprint/36605
DOI: 10.1021/ma101468r

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