The Diastereoselective Formation of Tetraalkoxy[4]resorcinarenes Derived from (-)-(2R)-2-Methoxy-2-phenylethanol and Proof of Absolute Configurations

Bulman Page, Philip C., Chan, Yohan, Heaney, Harry, McGrath, Matthew J. and Moreno, Eduardo (2011) The Diastereoselective Formation of Tetraalkoxy[4]resorcinarenes Derived from (-)-(2R)-2-Methoxy-2-phenylethanol and Proof of Absolute Configurations. European Journal of Organic Chemistry, 2011 (27). pp. 5347-5354. ISSN 1099-0690

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Abstract

The preparation of optically pure (-)-3-[(2R)-2-methoxy-2-phenylethoxy] phenol from resorcinol monobenzoate and its conversion into diastereoisomeric tetraalkoxyresorcin[4]arenes together with proof of the absolute configurations of the products is reported. The results of the study indicate that diastereoselective ring closure of linear tetrameric intermediates is controlled by the steric demand of the alkyl group in the precursor 3-alkoxyphenol.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Users 2731 not found.
Date Deposited: 26 Sep 2011 13:53
Last Modified: 21 Apr 2020 16:33
URI: https://ueaeprints.uea.ac.uk/id/eprint/34895
DOI: 10.1002/ejoc.201100733

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