Imine-based vanadium catalysts for α-olefin polymerization

Redshaw, C. ORCID: https://orcid.org/0000-0002-2090-1688 (2011) Imine-based vanadium catalysts for α-olefin polymerization. Chemistry and Materials Science, 35. pp. 153-195. ISSN 0920-4652

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Abstract

Advances over the last decade in the development of vanadium-based pro-catalysts bearing ligands containing the imine functionality are discussed in terms of their synthesis, characterization and their ability to oligmerize/polymerize a-olefins. The chapter is organized by ligand type, considering initially ligands which chelate (bi- and tri-dentate) only through nitrogen centres, before discussing those binding via nitrogen and oxygen (bi-, tri- and tetra-dentate), those with nitrogen, oxygen and sulfur donors (penta- and hexa-dentate) and finally a number of ligand systems which are either mono-dentate or for which the term imine can be more loosely applied, such as the heterocycle pyridine.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
Depositing User:	Rachel Smith
Date Deposited:	21 Jul 2011 10:38
Last Modified:	18 Jun 2026 14:53
URI:	https://ueaeprints.uea.ac.uk/id/eprint/34015
DOI:	10.1007/978-90-481-3815-9_4

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