Imine-Based Vanadium Catalysts for α-Olefin Polymerization

Redshaw, C (2011) Imine-Based Vanadium Catalysts for α-Olefin Polymerization. Chemistry and Materials Science, 35. pp. 153-195. ISSN 0920-4652

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Advances over the last decade in the development of vanadium-based pro-catalysts bearing ligands containing the imine functionality are discussed in terms of their synthesis, characterization and their ability to oligmerize/polymerize a-olefins. The chapter is organized by ligand type, considering initially ligands which chelate (bi- and tri-dentate) only through nitrogen centres, before discussing those binding via nitrogen and oxygen (bi-, tri- and tetra-dentate), those with nitrogen, oxygen and sulfur donors (penta- and hexa-dentate) and finally a number of ligand systems which are either mono-dentate or for which the term imine can be more loosely applied, such as the heterocycle pyridine.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 21 Jul 2011 10:38
Last Modified: 22 Nov 2022 12:30
DOI: 10.1007/978-90-481-3815-9_4

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