In situ generation of 2-lodoxybenzoic acid (IBX) in the presence of tetraphenylphosphonium monoperoxysulfate (TPPP) for the conversion of primary alcohols into the corresponding aldehydes

Bulman Page, P. C. B., Appleby, L. F., Buckley, B. R., Allin, S. M. and McKenzie, M. J. (2007) In situ generation of 2-lodoxybenzoic acid (IBX) in the presence of tetraphenylphosphonium monoperoxysulfate (TPPP) for the conversion of primary alcohols into the corresponding aldehydes. Synlett (10). pp. 1565-1568. ISSN 0936-5214

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Abstract

Primary alcohols are oxidized to the corresponding aldehydes by tetraphenylphosphonium monoperoxysul fate (TPPP) in the presence of catalytic 2-iodobenzoic acid, Overoxidation to carboxylic acids is not observed, in contrast to the use of catalytic 2-iodobenzoic acid with Oxone (R) as reoxidant.

Item Type: Article
Uncontrolled Keywords: reagent,nonaqueous conditions,oxone (r),alcohol,tppp,dimethyl-sulfoxide,oxidation,oxone,oxidation,oxidant,aldehyde,ibx
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 20 Jun 2011 13:50
Last Modified: 21 Apr 2020 19:19
URI: https://ueaeprints.uea.ac.uk/id/eprint/32882
DOI: 10.1055/s-2007-982550

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