An ytterbium-catalysed intramolecular aldehyde-ene reaction approach to the guaianolide and pseudoguaianolide diterpenoids: Synthesis of the guaiane skeleton

Bulman Page, Philip C., Gambera, Giovanni, Hayman, Colin M. and Edgar, Mark (2006) An ytterbium-catalysed intramolecular aldehyde-ene reaction approach to the guaianolide and pseudoguaianolide diterpenoids: Synthesis of the guaiane skeleton. Synlett (20). pp. 3411-3414. ISSN 0936-5214

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Abstract

A convergent approach to a functionalised guaiane ring system, the core of the guaianolide and pseudoguaianolide diterpenes, is described. The synthesis utilises an intramolecular aldehydeene reaction as the key step.

Item Type: Article
Uncontrolled Keywords: sesquiterpene lactone,guaianolide,pseudoguaianolide,perhydroazulene,intramolecular ene reaction
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User: Rachel Smith
Date Deposited: 20 Jun 2011 14:49
Last Modified: 24 Oct 2022 01:44
URI: https://ueaeprints.uea.ac.uk/id/eprint/32876
DOI: 10.1055/s-2006-956461

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