New chiral iminium salt catalysts for asymmetric epoxidation

Bulman Page, P. C., Buckley, B. R., Rassias, G. A. and Blacker, A. J. (2006) New chiral iminium salt catalysts for asymmetric epoxidation. European Journal of Organic Chemistry, 2006 (3). pp. 803-813. ISSN 1434-193X

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A range of enantiomerically pure 4-substituted 5-amino-1,3dioxanes has been condensed with 2-(2-bromoethyl)benzaldehyde to produce chiral dihydroisoquinolinium salts, which are effective asymmetric catalysts for the epoxidation of simple alkenes, giving ees of up to 71 %. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).

Item Type: Article
Uncontrolled Keywords: iminium salt,catalyst,catalysis,asymmetric epoxidation
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User: Rachel Smith
Date Deposited: 20 Jun 2011 14:07
Last Modified: 24 Oct 2022 01:44
DOI: 10.1002/ejoc.200500756

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