Bulman Page, P. C. B., Heaney, H., Reignier, S. and Rassias, G. A. (2003) 1,2-aminothioethers derived from ephedrine and pseudoephedrine: Heterobidentate ligands for the palladium-catalysed asymmetric allylic substitution reaction. Synlett (1). pp. 22-28. ISSN 0936-5214
Full text not available from this repository. (Request a copy)Abstract
Heterobidentate sulfide-tertiary amine ligands incorporating 1,2-aminothioethers derived from ephedrine and pseudoephedrine have been prepared and used successfully in the palladium-catalysed asymmetric allylic substitution reaction, giving ees of up to 89%. The stereoelectronic effects operating in the reactions are discussed.
Item Type: | Article |
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Uncontrolled Keywords: | chiral,alkylation,ligands,enantioselective catalysis,ephedrine,heterobidentate ligands,nuclear-magnetic-resonance,chelate ligands,amination,containing oxazoline ligands,metal-complexes,allylic substitution,hybrid ligands,(eta-3-allyl)palladium complexes |
Faculty \ School: | Faculty of Science > School of Chemistry |
Depositing User: | Rachel Smith |
Date Deposited: | 21 Jun 2011 10:06 |
Last Modified: | 24 Oct 2022 02:53 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/32848 |
DOI: |
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