The desymmetrisation of resorcinol: The synthesis of resorcinol monoalkyl ethers

Boxhall, Jonathan Y., Bulman Page, Philip C., Chan, Yohan, Hayman, Colin M., Heaney, Harry and McGrath, Matthew J. (2003) The desymmetrisation of resorcinol: The synthesis of resorcinol monoalkyl ethers. Synlett (7). pp. 997-1001. ISSN 0936-5214

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Abstract

The desymmetrisation of resorcinol to give 3-alkoxyresorcinol derivatives can be achieved in excellent yields either from resorcinol monobenzoate and alcohols using Mitsunobu reactions followed by hydrolysis using a strong base or by using 3-iodophenylbenzyl ether as a resorcinol monobenzyl ether equivalent in reactions with alcohols catalysed by copper(I)-9,10-phenanthroline followed by ammonium formate-palladium catalysed hydrogenolysis.

Item Type: Article
Uncontrolled Keywords: mitsunobu reactions,aryl,calix<4>resorcinarene derivatives,caesium carbonate,hydrolyses,analogs,phosphate,kadsurenone,9,copper(i) iodide,10-phenanthroline
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 21 Jun 2011 10:46
Last Modified: 10 Jun 2020 23:47
URI: https://ueaeprints.uea.ac.uk/id/eprint/32843
DOI: 10.1055/s-2003-39293

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