N-oxidation of pyridines by hydrogen peroxide in the presence of TS-1

Robinson, D. J., McMorn, P., Bethell, D., Bulman Page, P. C. B, Sly, C., King, F., Hancock, F. E. and Hutchings, G. J. (2001) N-oxidation of pyridines by hydrogen peroxide in the presence of TS-1. Catalysis Letters, 72 (3-4). pp. 233-234. ISSN 1011-372X

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Abstract

In the production of aromatic N-oxides using the oxidation of N-containing heterocyclic aromatic substrates with H2O2 as oxidant, the non-catalysed homogeneous oxidation is found to play an important part in the overall reaction. In addition, when TS-1 is used as a catalyst, there are many potential competitive interactions between the catalyst, the reactants and the products, which limit the effectiveness of the catalyst. It is concluded that the use of TS-1 and other microporous catalysts for the heterogeneous N-oxidation of pyridine and substituted pyridines needs to be interpreted with caution.

Item Type: Article
Uncontrolled Keywords: catalysts,n-oxidation of pyridine,catalysis,uncatalysed oxygen transfer,hydrogen peroxide,ts-1,heterogeneous
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 21 Jun 2011 11:24
Last Modified: 21 Apr 2020 21:07
URI: https://ueaeprints.uea.ac.uk/id/eprint/32830
DOI:

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