Functionalized iminium salt systems for catalytic asymmetric epoxidation

Bulman Page, P. C. B., Rassias, G. A., Barros, D., Ardakani, A., Buckley, B., Bethell, D., Smith, T. A. D. and Slawin, A. M. Z. (2001) Functionalized iminium salt systems for catalytic asymmetric epoxidation. Journal of Organic Chemistry, 66 (21). pp. 6926-6931. ISSN 0022-3263

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A range of dihydroisoquinolinium salts containing alcohol, ether, and acetal functionalities in the nitrogen substituent has been prepared and tested as asymmetric epoxidation catalysts, providing ee's of up to ca. 60%.

Item Type: Article
Uncontrolled Keywords: hydrogen-peroxide,alkene epoxidation,system,synthetic enzymes,highly enantioselective epoxidation,chiral oxaziridinium salt,efficient epoxidation,n-sulfonyloxaziridines,oxygen-transfer,unfunctionalized olefins,triphase
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 21 Jun 2011 11:23
Last Modified: 24 Oct 2022 03:34
DOI: 10.1021/jo010258n

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