NMR study of the effect of electron beam processing on a poly(ether-block-amide)

Clayden, N. J. and Pendlebury, R. (2001) NMR study of the effect of electron beam processing on a poly(ether-block-amide). Polymer, 42 (20). pp. 8373-8377. ISSN 0032-3861

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Abstract

H-1 T-1 and T-1p measurements together with FID function fitting were used to investigate the effect of electron beam irradiation on the dynamics of a poly(ether-block-amide). Rigid polyamide and mobile polyether phases art: seen in the FID of the control polymer. Irradiation causes a decrease in mobility of the mobile phase. Spin diffusion evident in the T-1 and T-1p shows qualitatively a phase separated morphology on the 2 nm scale and prevents a clear interpretation of the changes caused by irradiation. Only minor differences were seen in the C-13 CPMAS NMR spectra of the control and irradiated polymers. (C) 2001 Elsevier Science Ltd. All rights reserved.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 15 Jun 2011 11:28
Last Modified: 11 May 2020 23:49
URI: https://ueaeprints.uea.ac.uk/id/eprint/32495
DOI: 10.1016/S0032-3861(01)00251-8

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