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Roe, C., Sandoe, E. J. and Stephenson, G. R. 
ORCID: https://orcid.org/0000-0003-1487-9178
(2010)
Solvolysis reactions at the 13th carbon of 1-aryl organoiron complexes.
Tetrahedron Letters, 51 (4).
pp. 591-595.
ISSN 0040-4039
Abstract
Acid-catalysed solvolysis procedures exchange protecting groups on benzyl alcohol derivatives in the synthesis of eta(5) 1-arylcyclohexadienyliron building blocks for alkaloid synthesis. The reaction proceeds via a carbocation intermediate which can also be intercepted by intramolecular electrophilic addition to the tricarbonyl(eta(4)-diene)iron(0) moiety to provide a novel and high-yielding cyclisation reaction forming a 5a alpha-cyanomethyl-5a,8a-dihydrofluorene tricarbonyliron complex in 96% yield. (C) 2009 Elsevier Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Additional Information: | Roe, Caroline Sandoe, Elizabeth J. Stephenson, G. Richard |
| Faculty \ School: | Faculty of Science > School of Chemistry |
| Depositing User: | Rachel Smith |
| Date Deposited: | 08 Jun 2011 10:44 |
| Last Modified: | 23 Oct 2022 01:37 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/32018 |
| DOI: | 10.1016/j.tetlet.2009.11.052 |
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