Silver-sensitive enantioselectivity in asymmetric Heck reactions

McDermott, Michael C., Stephenson, G. Richard ORCID: https://orcid.org/0000-0003-1487-9178 and Walkington, Andrew J. (2007) Silver-sensitive enantioselectivity in asymmetric Heck reactions. Synlett (1). pp. 51-54. ISSN 0936-5214

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Abstract

Amine- and pure Ag(I)-promoted asymmetric Heck cyclisations of 2-iodobut-2-enanilide 1 both gave the oxindole product (R)-(+)-2 in relatively low ee but the partial reduction of the silver salt promoted a substantially more stereocontrolled route to (S)-(-)-2 in a reaction in which the use of Strem Atg(3)PO(4) gave the R-product and Aldrich Ag3PO4 gave the S-product.

Item Type:	Article
Additional Information:	McDermott, Michael C. Stephenson, G. Richard Walkington, Andrew J.
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis (former - to 2025) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	08 Jun 2011 10:48
Last Modified:	18 Jun 2026 15:24
URI:	https://ueaeprints.uea.ac.uk/id/eprint/32011
DOI:	10.1055/s-2006-958447

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