Cationic (eta(6)-arene)tricarbonylmanganese linked to neutral (eta(6)-arene)tricarbonylchromium complexes

Schouteeten, Stéphanie, Tranchier, Jean-Philippe, Rose-Munch, Françoise, Rose, Eric, Auffrant, Audrey and Stephenson, G. Richard (2004) Cationic (eta(6)-arene)tricarbonylmanganese linked to neutral (eta(6)-arene)tricarbonylchromium complexes. Organometallics, 23 (18). pp. 4308-4316. ISSN 0276-7333

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Abstract

Palladium-catalyzed Sonogashira coupling reactions of the neutral [eta(5)(1-5)-1-ethynyl-4-methoxycyclohexa-2,4-dienyl]tricarbonylmanganes e(I) (4) and (eta(6)-chlorobenzene)tricarbonylchromium (5) yields the dinuclear 1-[eta(6)-phenylethynyl]tricarbonylchromium-[eta(5)(1-5)-methoxycyclohex a-2,4-dienyl]tricarbonylmanganese complex 6, which upon hydride abstraction affords the corresponding dinuclear diphenylacetylene eta(6)-Mn/eta(6)-Cr complex 7. This study has been extended to the case of dinuclear eta(6)-Mn/eta(6)-Cr linked to different spacers comprising a thiophene, a triple bond, or a combination of them.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 08 Jun 2011 11:06
Last Modified: 21 Apr 2020 20:23
URI: https://ueaeprints.uea.ac.uk/id/eprint/32006
DOI: 10.1021/om049807g

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