Schouteeten, Stéphanie, Tranchier, Jean-Philippe, Rose-Munch, Françoise, Rose, Eric, Auffrant, Audrey and Stephenson, G. Richard ORCID: https://orcid.org/0000-0003-1487-9178
(2004)
Cationic (eta(6)-arene)tricarbonylmanganese linked to neutral (eta(6)-arene)tricarbonylchromium complexes.
Organometallics, 23 (18).
pp. 4308-4316.
ISSN 0276-7333
Abstract
Palladium-catalyzed Sonogashira coupling reactions of the neutral [eta(5)(1-5)-1-ethynyl-4-methoxycyclohexa-2,4-dienyl]tricarbonylmanganes e(I) (4) and (eta(6)-chlorobenzene)tricarbonylchromium (5) yields the dinuclear 1-[eta(6)-phenylethynyl]tricarbonylchromium-[eta(5)(1-5)-methoxycyclohex a-2,4-dienyl]tricarbonylmanganese complex 6, which upon hydride abstraction affords the corresponding dinuclear diphenylacetylene eta(6)-Mn/eta(6)-Cr complex 7. This study has been extended to the case of dinuclear eta(6)-Mn/eta(6)-Cr linked to different spacers comprising a thiophene, a triple bond, or a combination of them.
Item Type: | Article |
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Faculty \ School: | Faculty of Science > School of Chemistry |
Depositing User: | Rachel Smith |
Date Deposited: | 08 Jun 2011 11:06 |
Last Modified: | 24 Oct 2022 02:46 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/32006 |
DOI: | 10.1021/om049807g |
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