Do pentaurea calix[5]arenes form hydrogen bonded dimeric capsules?

Thondorf, I., Broda, F., Vysotsky, M., Matthews, S. E. ORCID: https://orcid.org/0000-0001-8821-0851, Mogck, O. and Bohmer, V. (2005) Do pentaurea calix[5]arenes form hydrogen bonded dimeric capsules? Journal of Structural Chemistry, 46 (Supplement 1). S39-S45. ISSN 0022-4766

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Abstract

Calix[5]arenes substituted at their wider rim by five urea residues do not form hydrogen bonded dimeric capsules in aprotic, apolar solvents, in contrast to their calix[4]arene analogs, although molecular dynamic simulations predict very similar geometrical parameters for both cases. The reason for this different behavior is most probably the higher energetic cost which must be paid to arrange the calix[5]arene skeleton in the C-5-symmetrical conformation required for the dimerization.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Pharmacy
UEA Research Groups:	Faculty of Science > Research Groups > Medicinal Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemical Biology and Medicinal Chemistry (former - to 2021)
Depositing User:	Rachel Smith
Date Deposited:	26 May 2011 10:37
Last Modified:	24 Oct 2022 02:28
URI:	https://ueaeprints.uea.ac.uk/id/eprint/31451
DOI:	10.1007/s10947-006-0149-3

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