A comparative review of inorganic aerosol thermodynamic equilibrium modules: similarities, differences, and their likely causes

Zhang, Yang, Seigneur, Christian, Seinfeld, John H., Jacobson, Mark, Clegg, Simon L. and Binkowski, Francis S. (2000) A comparative review of inorganic aerosol thermodynamic equilibrium modules: similarities, differences, and their likely causes. Atmospheric Environment, 34 (1). pp. 117-137.

Full text not available from this repository. (Request a copy)

Abstract

A comprehensive comparison of five inorganic aerosol thermodynamic equilibrium modules, MARS-A, SEQUILIB, SCAPE2, EQUISOLV II, and AIM2, was conducted for a variety of atmospheric concentrations of particulate matter (PM) constituents, relative humidities (RHs), and temperatures. Our results show that although the PM compositions and concentrations predicted by these modules are generally comparable under most conditions, significant discrepancies exist under some conditions, especially at high nitrate/chloride concentrations and low/medium RHs. As a consequence, the absolute differences in total PM concentrations predicted by these modules under all simulation conditions are 7.7–12.3% on average and as much as 68% for specific cases. The PM predictions are highly sensitive to changes in the molar ratios of ammonium to sulfate, nitrate to sulfate, and sodium chloride to sulfate, relative humidity, and temperature. The similarities and differences in simulation results predicted by the five modules are analyzed and the likely causes for these differences are discussed in detail. Recommendations are provided regarding the relative advantages of these modules, possible improvements of their performance, and applications in three-dimensional PM modeling studies.

Item Type: Article
Faculty \ School: Faculty of Science > School of Environmental Sciences
Depositing User: Rosie Cullington
Date Deposited: 16 May 2011 15:05
Last Modified: 21 Apr 2020 21:20
URI: https://ueaeprints.uea.ac.uk/id/eprint/30622
DOI: 10.1016/S1352-2310(99)00236-8

Actions (login required)

View Item View Item