Intermolecular Fermi resonance

Stride, John A., Dallin, Paul H. and Jayasooriya, Upali A. (2003) Intermolecular Fermi resonance. Journal of Chemical Physics, 119 (5). pp. 2747-2752. ISSN 0021-9606

Full text not available from this repository. (Request a copy)


The exceptionally broad feature at similar to3025 cm(-1) observed in the Raman spectrum of chloroform dissolved in liquid sulfur dioxide is shown to be due to the triple combination mode, nu(1)+nu(2)+nu(3), of sulfur dioxide gaining intensity by mixing with the fundamental C-H stretching mode of chloroform. Investigation of a number of similar systems shows that this broadening is unique to this system and is certainly not heterogeneous broadening due to C-H hydrogen bonding to SO2. This therefore is probably the first observation of the phenomenon of intermolecular Fermi resonance, between molecularly distinct species. (C) 2003 American Institute of Physics.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Physical and Analytical Chemistry (former - to 2017)
Depositing User: Rachel Smith
Date Deposited: 09 May 2011 12:33
Last Modified: 24 Oct 2022 03:04
DOI: 10.1063/1.1587118

Actions (login required)

View Item View Item