Vibrational coupling in oxo-centred trinuclear clusters: oxygen-16/18 isotopic substitution studies of (Fe3O)-O-III(O2CC(CH3)(3))(6)(py)(3) FeCl4 and (Fe2FeO)-Fe-III-O-II(O2CC(CH3)(3))(6)(py)(3)

Wu, R. W., Jayasooriya, U. A. and Cannon, R. D. (2000) Vibrational coupling in oxo-centred trinuclear clusters: oxygen-16/18 isotopic substitution studies of (Fe3O)-O-III(O2CC(CH3)(3))(6)(py)(3) FeCl4 and (Fe2FeO)-Fe-III-O-II(O2CC(CH3)(3))(6)(py)(3). Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, 56 (3). pp. 575-579.

Full text not available from this repository. (Request a copy)

Abstract

IR spectra are reported for the compounds [Fe3O(O2CC(CH3)(3))(6)(py)(3)][FeCl4] and [Fe3O(O2CC(CH3)(3))(6)(py)(3)]. Using isotopic substitution at the central oxygen atom, the assignments of the in-plane and out-of-plane vibrations of this atom are confirmed, and coupling is demonstrated between the in-plane modes nu(as)(Fe3O) and carboxylate deformation modes rho(r)(C-CO2). (C) 2000 Elsevier Science B.V. All rights reserved.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 09 May 2011 11:30
Last Modified: 17 Sep 2020 23:51
URI: https://ueaeprints.uea.ac.uk/id/eprint/29778
DOI:

Actions (login required)

View Item View Item