Imine-based Vanadium Catalysts for alpha-olefin Polymerization

Redshaw, Carl (2011) Imine-based Vanadium Catalysts for alpha-olefin Polymerization. In: Catalysis by Metal Complexes #35: Olefin Upgrading Catalysis by Nitrogen-Based Metal Complexes I. Catalysis by Metal Complexes, 35 . Springer, pp. 153-195. ISBN 9789048138142

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Advances over the last decade in the development of vanadium-based pro-catalysts bearing ligands containing the imine functionality are discussed in terms of their synthesis, characterization and their ability to oligmerize/polymerize α-olefins. The chapter is organized by ligand type, considering initially ligands which chelate (bi- and tri-dentate) only through nitrogen centres, before discussing those binding via nitrogen and oxygen (bi-, tri- and tetra-dentate), those with nitrogen, oxygen and sulfur donors (penta- and hexa-dentate) and finally a number of ligand systems which are either mono-dentate or for which the term imine can be more loosely applied, such as the heterocycle pyridine.

Item Type: Book Section
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 11 Apr 2011 12:12
Last Modified: 21 Nov 2022 09:30
DOI: 10.1007/978-90-481-3815-9_4

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