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Bew, Sean P. 
ORCID: https://orcid.org/0000-0002-9087-9463, Carrington, Rachel, Hughes, David L., Liddle, John and Pesce, Paolo
(2009)
An Organocatalytic Synthesis ofcis-N-Alkyl- andN-Arylaziridine Carboxylates.
Advanced Synthesis & Catalysis, 351 (16).
pp. 2579-2588.
ISSN 1615-4150
Abstract
An extremely mild protocol that employs readily available starting materials, i.e., aldehyde, amine and alkyl diazoacetate, returns structurally diverse N-substituted-C-2/3-difunctionalised aziridines in excellent yields and stereoselectivities when pyridinium triflate is incorporated as an organocatalyst. The reaction process is environmentally benign affording water and nitrogen as the only by-products. This racemic protocol paves the way for the development of novel asymmetric organocatalysts capable of generating optically active aziridines.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| Depositing User: | Rachel Smith |
| Date Deposited: | 07 Apr 2011 09:46 |
| Last Modified: | 23 Oct 2022 01:46 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/28345 |
| DOI: | 10.1002/adsc.200900474 |
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