Electroanalytical Determination of Cadmium(II) and Lead(II) Using an Antimony Nanoparticle Modified Boron-Doped Diamond Electrode

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Toghill, Kathryn E., Xiao, Lei, Wildgoose, Gregory and Compton, Richard G. (2009) Electroanalytical Determination of Cadmium(II) and Lead(II) Using an Antimony Nanoparticle Modified Boron-Doped Diamond Electrode. Electroanalysis, 21 (10). pp. 1113-1118. ISSN 1521-4109

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Abstract

We report the simultaneous electroanalytical determination of Pb2+ and Cd2+ by linear sweep anodic stripping voltammetry (LSASV) using an antimony nanoparticle modified boron doped diamond (Sb-BDD) electrode. Sb deposition was performed in situ with the analytes, from a solution of 1 mg L-1 SbCl3 in 0.1 M HCl (pH 1). Pb2+ inhibited the detection of Cd2+ during simultaneous additions at the bare BDD electrode, whereas in the presence of antimony, both peaks were readily discernable and quantifiable over the linear range 50–500 µg L-1.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
Related URLs:	http://dx.doi.org/10.1002/elan.200904547
Depositing User:	Rachel Smith
Date Deposited:	29 Mar 2011 16:31
Last Modified:	02 Oct 2022 06:36
URI:	https://ueaeprints.uea.ac.uk/id/eprint/27477
DOI:	10.1002/elan.200904547

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