Can we measure catalyst efficiency in asymmetric chemical reactions? A theoretical approach

El-Fayyoumy, Shaimaa, Todd, Matthew H and Richards, Chris (2009) Can we measure catalyst efficiency in asymmetric chemical reactions? A theoretical approach. Beilstein Journal of Organic Chemistry, 5 (8). pp. 1726-1740. ISSN 1860-5397

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Abstract

The discovery that palladacycles are efficient catalysts for the allylic imidate rearrangement has resulted in the successful application of several such complexes to this reaction based on planar chiral iron and cobalt containing metallocenes. These palladacycles enable the efficient and highly enantioselective synthesis of a wide variety of protected allylic amines, which are valuable building blocks for use in asymmetric synthesis.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Related URLs:
Depositing User: Rachel Smith
Date Deposited: 29 Mar 2011 10:30
Last Modified: 21 Apr 2020 17:35
URI: https://ueaeprints.uea.ac.uk/id/eprint/27396
DOI: 10.3762/bjoc.5.67

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