Arylboron complexes of the acids Ph2C(XH)CO2H (X = O, NH)

Arbaoui, Abdessamad, Redshaw, Carl, Hughes, David L. and Elsegood, Mark R. J. (2009) Arylboron complexes of the acids Ph2C(XH)CO2H (X = O, NH). Inorganica Chimica Acta, 362 (2). pp. 509-514. ISSN 0020-1693

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The acids Ph2C(XH)CO2H (X = O, NH) readily react with the triarylboron reagents BAr3 (Ar = Ph, C6F5) to form the complexes [Ph2C(O)CO2BPh] and [Ph2C(NH2)CO2BPh2], Ph2C(p-CH3C6H4)CO2H [in the presence of Et3N the complex HNEt3[Ph2C(OH)CO2B(C6F5)3] (3b) was formed], and [Ph2C(NH3)CO2B(C6F5)3], respectively.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 24 Mar 2011 15:14
Last Modified: 06 Jan 2023 10:32
DOI: 10.1016/j.ica.2008.04.050

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