Multinuclear alkylaluminium macrocyclic Schiff base complexes: influence of procatalyst structure on the ring opening polymerisation of ε-caprolactone

Arbaoui, Abdessamad, Redshaw, Carl ORCID: https://orcid.org/0000-0002-2090-1688 and Hughes, David L. (2008) Multinuclear alkylaluminium macrocyclic Schiff base complexes: influence of procatalyst structure on the ring opening polymerisation of ε-caprolactone. Chemical Communications (39). pp. 4717-4719. ISSN 1364-548X

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Abstract

Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited beneficial cooperative effects, whilst aluminoxane-type bonding proved to be detrimental to activity for the ring opening polymerisation of e-caprolactone.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
Depositing User:	Rachel Smith
Date Deposited:	24 Mar 2011 15:32
Last Modified:	18 Jun 2026 15:14
URI:	https://ueaeprints.uea.ac.uk/id/eprint/27148
DOI:	10.1039/B810417D

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