Bis(imido) rhenium complexes bearing C- or N-capped ‘tripodal’ ligands: Bi- versus tri-dentate ligation

Redshaw, Carl, Zhan, Shu-Zhong, Dale, Sophie H. and Elsegood, Mark R.J. (2008) Bis(imido) rhenium complexes bearing C- or N-capped ‘tripodal’ ligands: Bi- versus tri-dentate ligation. Inorganic Chemistry Communications, 11 (7). pp. 754-756.

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Abstract

The differing geometrical constraints of the tripodal ligands tris(hydroxyphenyl)amine (N-cappedH3) and tris(3,5-di-t-Bu-2-hydroxyphenyl)methane (C-cappedH3) led, on reaction with [Re(t-BuN)3(OSiMe3)], to the isolation of the complexes [Re(t-BuN)2(N-capped)] (1) and [Re(OSiMe3)(t-BuN)2(C-cappedH)] (2), respectively. Both 1 · 1/2MeCN and 2 have been structurally characterized using X-ray synchrotron radiation.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Related URLs:
Depositing User: Rachel Smith
Date Deposited: 24 Mar 2011 15:48
Last Modified: 21 Apr 2020 17:54
URI: https://ueaeprints.uea.ac.uk/id/eprint/27145
DOI: 10.1016/j.inoche.2008.03.020

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