Organocatalysis of asymmetric epoxidation by iminium salts using sodium hypochlorite as the stoichiometric oxidant
Bulman Page, Philip, Parker, Phillip, Buckley, Benjamin R., Rassias, Gerasimos A. and Bethell, Donald (2009) Organocatalysis of asymmetric epoxidation by iminium salts using sodium hypochlorite as the stoichiometric oxidant. Tetrahedron, 65 (15). pp. 2910-2915.
Full text not available from this repository. (Request a copy)Abstract
Iminium salts can provide high selectivity and high efficiency when used as organocatalysts for asymmetric epoxidation. For this purpose, they are normally used in conjunction with Oxone as the stoichiometric oxidant. Oxone, however, has limited stability, is insoluble in most organic solvents, is atom-inefficient, and produces considerable inorganic residue as the by-product of oxidation. In this paper we report for the first time the development of a reaction system driven by sodium hypochlorite as the stoichiometric oxidant.
Item Type: | Article |
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Faculty \ School: | Faculty of Science > School of Chemistry |
Related URLs: | |
Depositing User: | Rachel Smith |
Date Deposited: | 22 Mar 2011 12:27 |
Last Modified: | 27 Apr 2022 04:35 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/26838 |
DOI: | 10.1016/j.tet.2009.02.007 |
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