Detection of the N3 free radical by laser magnetic resonance at 6.08 μm

Pahnke, Ralph, Ashworth, Stephen H. and Brown, John M. (1988) Detection of the N3 free radical by laser magnetic resonance at 6.08 μm. Chemical Physics Letters, 147 (2-3). pp. 179-182.

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Abstract

Lines in the ?3 (antisymmetric stretch) fundamental band of the N3 radical in the 2?g state have been detected by CO laser magnetic resonance. The observations have been assigned to P, Q, and R lines in the fundamental vibration-rotation band and lead to a precise determination of the vibrational interval, the ground-state rotational constant and its dependence on the antisymmetric stretching vibration: ?3 = 1644.67903(24) cm-1, B0=0.431438(16) cm-1 and a3=0.004357(18) cm-1.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Centre for Ocean and Atmospheric Sciences Faculty of Science > Research Groups > Physical and Analytical Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	08 Feb 2011 16:35
Last Modified:	28 Mar 2025 05:09
URI:	https://ueaeprints.uea.ac.uk/id/eprint/21139
DOI:	10.1016/0009-2614(88)85079-6

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