Room-Temperature Metal−Hydride Discharge Source, with Observations on NiH and FeH†

Vallon, Raphaël, Ashworth, Stephen, Crozet, Patrick, Field, Robert W., Forthomme, Damien, Harker, Heather, Richard, Cyril and Ross, Amanda J. (2009) Room-Temperature Metal−Hydride Discharge Source, with Observations on NiH and FeH†. The Journal of Physical Chemistry A, 113 (47). pp. 13159-13166.

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Abstract

A metal sputtering source suitable for laboratory production of metal hydrides is described. Sputtering from pure nickel or iron in an Ar/H2 discharge is analyzed at low resolution. High resolution laser excitation and dispersed fluorescence spectra of NiH have also been recorded. The source has been designed to operate with a ferromagnetic circuit for Zeeman spectroscopy. Signals from the source are strong enough to record dispersed fluorescence from NiH by Fourier transform interferometry in magnetic fields up to 1 T. We establish that FeH can also be formed in this source.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Related URLs:
Depositing User: Rachel Smith
Date Deposited: 10 Feb 2011 16:24
Last Modified: 24 Jul 2019 14:48
URI: https://ueaeprints.uea.ac.uk/id/eprint/21117
DOI: 10.1021/jp9033968

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