Chlorine isotope fractionation in the stratosphere

Laube, JC, Kaiser, J ORCID: https://orcid.org/0000-0002-1553-4043, Sturges, WT ORCID: https://orcid.org/0000-0002-9044-7169, Bonisch, H and Engel, A (2010) Chlorine isotope fractionation in the stratosphere. Science, 329 (5996). p. 1167. ISSN 1095-9203

Preview

PDF (Laube et al. Science 2010 Chlorine isotope fractionation in the stratosphere_AAM) - Accepted Version Download (313kB) | Preview

Abstract

Chlorinated organic compounds are important contributors to the anthropogenic enhancement of stratospheric ozone depletion. We report measurements of stratospheric isotope fractionation in such a compound. Stratospheric and tropospheric difluorodichloromethane (CF2Cl2) were found to have the largest relative 37Cl/35Cl isotope ratio difference ever measured for a natural compound. The increase of the relative isotope ratio difference with altitude was tightly correlated to the corresponding decrease in the CF2Cl2 mixing ratio. The observed relationship has a high potential to provide new insights into atmospheric chemistry and transport processes.

Item Type:	Article
Uncontrolled Keywords:	sdg 12 - responsible consumption and production ,/dk/atira/pure/sustainabledevelopmentgoals/responsible_consumption_and_production
Faculty \ School:	Faculty of Science > School of Environmental Sciences University of East Anglia Research Groups/Centres > Theme - ClimateUEA
UEA Research Groups:	Faculty of Science > Research Groups > Marine and Atmospheric Sciences (former - to 2017) Faculty of Science > Research Groups > Atmospheric Chemistry (former - to 2018) Faculty of Science > Research Groups > Climate, Ocean and Atmospheric Sciences (former - to 2017) Faculty of Science > Research Groups > Centre for Ocean and Atmospheric Sciences
Depositing User:	Rosie Cullington
Date Deposited:	15 Feb 2011 11:58
Last Modified:	20 Mar 2023 10:32
URI:	https://ueaeprints.uea.ac.uk/id/eprint/20344
DOI:	10.1126/science.1191809

Downloads

Actions (login required)

View Item