Unexpected mesophase behaviour in novel triphenylene multi-alkenes

Cammidge, Andrew N., Beddall, Alison R. and Gopee, Hemant (2007) Unexpected mesophase behaviour in novel triphenylene multi-alkenes. Tetrahedron Letters, 48 (38). pp. 6700-6703.

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Abstract

The first series of hexaalkenyloxytriphenylenes, where the unsaturation resides at the termini of the side chains, has been synthesised and characterised. Most interestingly, the synthesis of these alkenyloxytriphenylenes, by alkylation of hexahydroxytriphenylene, is found to yield additional products resulting from a single C-alkylation alongside exhaustive O-alkylation; surprisingly several homologues of these materials retain columnar mesophase behaviour.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy
Depositing User:	Rachel Smith
Date Deposited:	31 Jan 2011 16:56
Last Modified:	28 Mar 2025 03:46
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10984
DOI:	10.1016/j.tetlet.2007.07.097

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