Phthalocyanines bearing bulky cycloalkylmethyl substituents on non-peripheral sites

Cammidge, Andrew N., Tseng, Chiung-Hui, Chambrier, Isabelle, Hughes, David L. and Cook, Michael J. (2009) Phthalocyanines bearing bulky cycloalkylmethyl substituents on non-peripheral sites. Tetrahedron Letters, 50 (37). pp. 5254-5256.

Full text not available from this repository. (Request a copy)

Abstract

Octasubstituted phthalocyanines bearing bulky (cyclopentyl)methyl- and (cyclohexyl)methyl-substituents in non-peripheral positions are prepared and characterised. The synthesis of the precursor phthalonitriles is achieved through nickel-catalysed cross-coupling employing alkylzinc reagents. In the case of the (cyclopentyl)methyl derivative the formal precursor is 5-hexenyl bromide which yields the cyclised material exclusively on formation of the zinc reagent and subsequent cross-coupling.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 01 Feb 2011 12:45
Last Modified: 28 Oct 2019 15:39
URI: https://ueaeprints.uea.ac.uk/id/eprint/10979
DOI: 10.1016/j.tetlet.2009.07.016

Actions (login required)

View Item View Item