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Cammidge, Andrew N. 
ORCID: https://orcid.org/0000-0001-7912-4310, Tseng, Chiung-Hui, Chambrier, Isabelle, Hughes, David L. and Cook, Michael J.
(2009)
Phthalocyanines bearing bulky cycloalkylmethyl substituents on non-peripheral sites.
Tetrahedron Letters, 50 (37).
pp. 5254-5256.
Abstract
Octasubstituted phthalocyanines bearing bulky (cyclopentyl)methyl- and (cyclohexyl)methyl-substituents in non-peripheral positions are prepared and characterised. The synthesis of the precursor phthalonitriles is achieved through nickel-catalysed cross-coupling employing alkylzinc reagents. In the case of the (cyclopentyl)methyl derivative the formal precursor is 5-hexenyl bromide which yields the cyclised material exclusively on formation of the zinc reagent and subsequent cross-coupling.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| UEA Research Groups: | Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy |
| Depositing User: | Rachel Smith |
| Date Deposited: | 01 Feb 2011 12:45 |
| Last Modified: | 12 May 2023 09:30 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/10979 |
| DOI: | 10.1016/j.tetlet.2009.07.016 |
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