Zinc(II) η1- and η2-Toluene Complexes: Structure and Bonding in Zn(C6F5)2·(toluene) and Zn(C6F4-2-C6F5)2·(toluene)

Guerrero, Antonio, Martin, Eddy, Hughes, David L., Kaltsoyannis, Nikolas and Bochmann, Manfred (2006) Zinc(II) η1- and η2-Toluene Complexes: Structure and Bonding in Zn(C6F5)2·(toluene) and Zn(C6F4-2-C6F5)2·(toluene). Organometallics, 25 (14). pp. 3311-3313.

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Abstract

The first structural characterization of toluene complexes of zinc is reported. The (perfluoroaryl)zinc compounds Zn(C6F5)2·(toluene) and Zn(C6F4-2-C6F5)2·(toluene) show toluene in ?2 and ?1 coordination modes, respectively. On the other hand, charge distribution calculations, Mulliken overlap population analysis, and bonding energy data suggest that the interactions between the Zn and the toluene ring are rather similar in both cases.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 02 Nov 2010 17:48
Last Modified: 03 Oct 2019 14:30
URI: https://ueaeprints.uea.ac.uk/id/eprint/10531
DOI: 10.1021/om060429k

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