Copolymerization of Propene and 5-Vinyl-2-Norbornene: A Simple Route to Polar Poly(propylene)s

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Sarazin, Y, Fink, G, Hauschild, K and Bochmann, M ORCID: https://orcid.org/0000-0001-7736-5428 (2005) Copolymerization of Propene and 5-Vinyl-2-Norbornene: A Simple Route to Polar Poly(propylene)s. Macromolecular Rapid Communications, 26 (15). pp. 1208-1213. ISSN 1022-1336

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Abstract

The metallocenes rac-C2H4(Ind)2ZrCl2 ( 1 ), rac-Me2Si(Ind)2ZrCl2 ( 2 ), and rac-Me2Si(2-Me-benz[e]Ind)2ZrCl2 ( 3 ) efficiently copolymerize propene and 5-vinyl-2-norbornene (VNB). 1 and 2 give a high VNB content and high productivities, whereas 3 gives moderate incorporation. Surprisingly, precatalysts 1 and 2 , which have very closely related structures, showed very different reactivities toward VNB, with 1 having a greater affinity for VNB than for propene. The copolymers are quantitatively converted into polyolefins with polar functionalities

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
Related URLs:	http://dx.doi.org/10.1002/marc.200500241
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	24 Oct 2022 02:26
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10513
DOI:	10.1002/marc.200500241

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