Woodman, TJ, Schormann, M, Hughes, DL and Bochmann, M ORCID: https://orcid.org/0000-0001-7736-5428
(2003)
New Bulky Allyl Complexes of Lanthanide Metals: Role of Alkali-Metal Cations in Controlling Solid-State and Solution Assemblies in Precatalysts.
Organometallics, 22 (15).
pp. 3028-3030.
Abstract
The reaction of the bulky allyl anion [1,3-C3H3(SiMe3)2]- with SmI2(THF)2 gives the allyl-bridged dimer [Sm(C3H3(SiMe3)2)3{µ-K(THF)2}]2, the first structurally authenticated Sm(II) allyl complex. The compound is a highly effective single-component catalyst for the polymerization of methyl methacrylate and e-caprolactone.
Item Type: | Article |
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Faculty \ School: | Faculty of Science > School of Chemistry |
Related URLs: | |
Depositing User: | Rachel Smith |
Date Deposited: | 02 Nov 2010 17:48 |
Last Modified: | 24 Oct 2022 02:51 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/10493 |
DOI: | 10.1021/om030283e |
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