Synthesis and catalytic activity of three-coordinate zinc cations

Hannant, Mark D., Schormann, Mark and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2002) Synthesis and catalytic activity of three-coordinate zinc cations. Journal of the Chemical Society, Dalton Transactions (22). pp. 4071-4073. ISSN 0300-9246

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Abstract

Reaction between DADZnR2 and either B(C6F5)3 or ZnR2 and [DADH][B(C6F5)4] affords three-coordinate alkyl and amide zinc cations which are active for the ring opening polymerisation of epoxides and e-caprolactone [DAD = (MeC=NC6H3Pri2-2,6)2].

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis (former - to 2025) Faculty of Science > Research Groups > Chemistry of Light and Energy (former - to 2025) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	18 Jun 2026 15:48
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10485
DOI:	10.1039/b208165m

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