[H2N{B(C6F5)3}2]-: A New, Remarkably Stable Diborate Anion for Metallocene Polymerization Catalysts

Lancaster, SJ, Rodriguez, A, Lara-Sanchez, A, Hannant, MD, Walker, DA, Hughes, D and Bochmann, M (2002) [H2N{B(C6F5)3}2]-: A New, Remarkably Stable Diborate Anion for Metallocene Polymerization Catalysts. Organometallics, 21 (3). pp. 451-453.

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Abstract

The reaction between NaNH2 and B(C6F5)3 affords the amidodiborate anion [H2N{B(C6F5)3}2]-, the structure of which shows multiple intramolecular NH···F hydrogen bonding. Reaction with HCl affords [H(OEt2)2][H2N{B(C6F5)3}2], while treatment of zirconocene dimethyls with [CPh3][H2N{B(C6F5)3}2] gives highly active alkene polymerization catalysts.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Related URLs:
Depositing User: Rachel Smith
Date Deposited: 02 Nov 2010 17:48
Last Modified: 24 Jul 2019 17:12
URI: https://ueaeprints.uea.ac.uk/id/eprint/10480
DOI: 10.1021/om010942s

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