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ToolsLancaster, Simon J., Rodriguez, Antonio, Lara-Sanchez, Agustin, Hannant, Mark D., Walker, Dennis A., Hughes, David and Bochmann, Manfred (2002) [H2N{B(C6F5)3}2]-: A new, remarkably stable diborate anion for metallocene polymerization catalysts. Organometallics, 21 (3). pp. 451-453. ISSN 1520-6041
Full text not available from this repository. (Request a copy)Abstract
The reaction between NaNH2 and B(C6F5)3 affords the amidodiborate anion [H2N{B(C6F5)3}2]-, the structure of which shows multiple intramolecular NH···F hydrogen bonding. Reaction with HCl affords [H(OEt2)2][H2N{B(C6F5)3}2], while treatment of zirconocene dimethyls with [CPh3][H2N{B(C6F5)3}2] gives highly active alkene polymerization catalysts.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| UEA Research Groups: | Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy |
| Depositing User: | Rachel Smith |
| Date Deposited: | 02 Nov 2010 17:48 |
| Last Modified: | 28 Mar 2025 04:40 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/10480 |
| DOI: | 10.1021/om010942s |
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