Gold metallacages: Design principles and applications

Thomas, Sophie R. ORCID: https://orcid.org/0000-0003-1110-430X, Willnhammer, Nina, Casini, Angela and Moreno-Alcántar, Guillermo (2025) Gold metallacages: Design principles and applications. Chem, 11 (6). ISSN 2451-9294

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Abstract

Metallacages (MCgs) are three-dimensional (3D)-supramolecular coordination complexes (SCCs) obtained by the self-assembly of metal ions with donor ligands, which are arranged to delimit a cavity. Recently, the number of structural studies using gold ions in the construction of metallacages and the first efforts to design these systems for diverse applications have shed light on the potential of gold MCgs to become useful supramolecular systems in sensing and separation, catalysis, and medicine. This work critically revises the design principles of gold MCgs and their early applications, highlighting the main challenges and opportunities for developing functional assemblies.

Item Type: Article
Uncontrolled Keywords: sdg9: industry, innovation, and infrastructure,catalysis,gold,medicinal chemistry,metallacages,sensing,general chemistry,biochemistry,environmental chemistry,general chemical engineering,biochemistry, medical,materials chemistry ,/dk/atira/pure/subjectarea/asjc/1600/1600
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Depositing User: LivePure Connector
Date Deposited: 14 Sep 2026 09:54
Last Modified: 16 Sep 2026 11:14
URI: https://ueaeprints.uea.ac.uk/id/eprint/104510
DOI:

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