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Furney, Isaac J. and Wright, Joseph A. 
ORCID: https://orcid.org/0000-0001-9603-1001
(2025)
Synthesis and characterisation of MoIV-oxo dithiolenes: formate dehydrogenase active site mimetics.
Dalton Transactions, 54 (39).
pp. 14611-14617.
ISSN 1477-9226
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Abstract
The active sites of metalloenzymes continue to inspire synthetic chemists to create structural models of the intricate structures seen in biology. As well as the fundamental intellectual challenge, this is driven by the potential societal impact that many of these systems offer. Formate dehydrogenases (FDHs) hold such potential: formate is one of the key candidates as a hydrogen carrier for future energy transport. Efforts at mimicking the active site of FDH require the synthesis of (functionalised) molybdenum bis(dithiolene) complexes, principally featuring the Mo═O unit. In this review, we give an overview of the synthetic routes used to date in these efforts, along with key infrared and electrochemical data for the full collection of synthetic complexes reported to date.
| Item Type: | Article |
|---|---|
| Additional Information: | Data availability: No new data are presented in the manuscript: they are all taken from the primary literature. |
| Uncontrolled Keywords: | inorganic chemistry ,/dk/atira/pure/subjectarea/asjc/1600/1604 |
| Faculty \ School: | Faculty of Science > School of Chemistry, Pharmacy and Pharmacology |
| Related URLs: | |
| Depositing User: | LivePure Connector |
| Date Deposited: | 10 Aug 2026 15:06 |
| Last Modified: | 10 Aug 2026 15:06 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/104096 |
| DOI: | 10.1039/d5dt01233c |
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