Fine-tuning polyoxometalate non-linear optical chromophores: a molecular electronic “Goldilocks” effect

Al-Yasari, Ahmed, Spence, Philip, El Moll, Hani, Van Steerteghem, Nick, Horton, Peter N., Brunschwig, Bruce S., Clays, Koen and Fielden, John (2018) Fine-tuning polyoxometalate non-linear optical chromophores: a molecular electronic “Goldilocks” effect. Dalton Transactions, 47 (31). pp. 10415-10419. ISSN 1477-9226

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      Abstract

      A new aryl-imido polyoxometalate non-linear optical chromophore (POMophore) with a diphenylamino donor group attains the highest βzzz, 0 value (196 × 10−30 esu by Hyper-Rayleigh Scattering, HRS), and best transparency/non-linearity trade off yet for such materials. Stark spectroscopic and DFT investigation of this compound, plus NMe2 and carbazole analogues, show that its high performance results from a combination of strongly dipolar electronic transitions, and strong electronic communication across the π-system.

      Item Type: Article
      Faculty \ School: Faculty of Science > School of Chemistry
      Faculty of Science > School of Pharmacy
      Depositing User: Pure Connector
      Date Deposited: 17 May 2018 17:30
      Last Modified: 16 Feb 2019 00:59
      URI: https://ueaeprints.uea.ac.uk/id/eprint/67132
      DOI: 10.1039/C8DT01491D

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