Arene C-H activation by gold(III): Solvent-enabled proton shuttling, and observation of a pre-metallation Au-arene intermediate

Rocchigiani, Luca, Fernandez Cestau, Julio, Budzelaar, Peter and Bochmann, Manfred (2017) Arene C-H activation by gold(III): Solvent-enabled proton shuttling, and observation of a pre-metallation Au-arene intermediate. Chemical Communications, 53 (31). pp. 4358-4361. ISSN 1359-7345

[img] Microsoft Word (Accepted manuscript) - Submitted Version
Download (4MB)

    Abstract

    Selective Au-C bond cleavage and arene-C-H activation in (C^N^C)Au(III) pincer complexes are reversible, leading to a solvent-dependent proton shuttling process. The ether-free cleavage products are non-fluxional and show weak gold(III)-arene interactions commensurate with intermediates postulated previously for CMD-type arene activation.

    Item Type: Article
    Faculty \ School: Faculty of Science > School of Chemistry
    University of East Anglia > Faculty of Science > Research Groups > Synthetic Chemistry
    Depositing User: Pure Connector
    Date Deposited: 21 Apr 2017 06:10
    Last Modified: 25 Jul 2018 13:31
    URI: https://ueaeprints.uea.ac.uk/id/eprint/63269
    DOI: 10.1039/C7CC01628J

    Actions (login required)

    View Item