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ToolsNi, Xin-Long, Zeng, Xi, Hughes, David L., Redshaw, Carl and Yamato, Takehiko (2011) Synthesis, crystal structures and complexation behaviours ofthiacalix[4]arenes bearing 1,2,3-triazole groups. Supramolecular Chemistry, 23 (10). pp. 689-695. ISSN 1029-0478
Full text not available from this repository. (Request a copy)Abstract
The structure and complexation behaviour of 1,3-alternate-1,2,3-triazole based on thiacalix[4]arene,1,3-alternate-1 and 2 have been determined by means of X-ray analysis, fluorescence and 1H NMR spectroscopy. The X-ray results suggested that the nitrogen atom N3 on triazole ring can act as hydrogen bond acceptors in the self-assembly of a supramolecular structure. The fluorescence spectra changes indicated that the thiacalix[4]arene bearing 1,2,3-triazole groups were highly selective for Ag+ in comparison with other tested metal ions by enhancement of the monomer emission of pyrene. The 1H NMR results suggested that Ag+ can be strongly bonded by the triazole groups with the cooperation of the ionophoric cavity formed by the two inverted benzene rings and the sulfur atoms of the thiacalix[4]arene.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| Depositing User: | Pure Connector |
| Date Deposited: | 16 Nov 2015 15:00 |
| Last Modified: | 15 Dec 2022 01:27 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/55380 |
| DOI: | 10.1080/10610278.2011.601603 |
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