First examples of functionalisation of meso-aryl tetrabenzotriazaporphyrins (TBTAPs) through cross-coupling reactions

Alharbi, Nuha, Tizzard, Graham J., Coles, S. J., Cook, Mike and Cammidge, Andy (2015) First examples of functionalisation of meso-aryl tetrabenzotriazaporphyrins (TBTAPs) through cross-coupling reactions. Tetrahedron, 71 (39). 7227–7232. ISSN 0040-4020

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    Abstract

    Recent synthetic advances have given convenient access to tetrabenzotriazaporphyrins (TBTAPs) functionalised with meso-aryl substituents. In this paper we report the first examples of further functionalization of the meso-sites through Suzuki-Miyaura and copper-free Sonagashira cross-coupling reactions of the meso-(bromophenyl)TBTAPs, demonstrating the breadth of new materials design now possible in the hybrid macrocycles.

    Item Type: Article
    Uncontrolled Keywords: phthalocyanines,porphyrins,heterocycles,synthesis,hybrids,cross-coupling
    Faculty \ School: Faculty of Science > School of Chemistry
    Depositing User: Pure Connector
    Date Deposited: 24 Jul 2015 23:11
    Last Modified: 19 Apr 2019 00:57
    URI: https://ueaeprints.uea.ac.uk/id/eprint/53549
    DOI: 10.1016/j.tet.2015.03.095

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