First examples of functionalisation of meso-aryl tetrabenzotriazaporphyrins (TBTAPs) through cross-coupling reactions

Alharbi, Nuha, Tizzard, Graham J., Coles, S. J., Cook, Mike and Cammidge, Andy ORCID: https://orcid.org/0000-0001-7912-4310 (2015) First examples of functionalisation of meso-aryl tetrabenzotriazaporphyrins (TBTAPs) through cross-coupling reactions. Tetrahedron, 71 (39). 7227–7232. ISSN 0040-4020

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Abstract

Recent synthetic advances have given convenient access to tetrabenzotriazaporphyrins (TBTAPs) functionalised with meso-aryl substituents. In this paper we report the first examples of further functionalization of the meso-sites through Suzuki-Miyaura and copper-free Sonagashira cross-coupling reactions of the meso-(bromophenyl)TBTAPs, demonstrating the breadth of new materials design now possible in the hybrid macrocycles.

Item Type: Article
Uncontrolled Keywords: phthalocyanines,porphyrins,heterocycles,synthesis,hybrids,cross-coupling
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Faculty of Science > Research Groups > Chemistry of Light and Energy
Depositing User: Pure Connector
Date Deposited: 24 Jul 2015 22:11
Last Modified: 12 May 2023 09:31
URI: https://ueaeprints.uea.ac.uk/id/eprint/53549
DOI: 10.1016/j.tet.2015.03.095

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