Diastereoselective synthesis of half-sandwich chiral-at-metal cobaltacycles by oxidative cyclisation

Amin, J and Richards, C (2012) Diastereoselective synthesis of half-sandwich chiral-at-metal cobaltacycles by oxidative cyclisation. Chemical Communications, 48. pp. 10192-10194. ISSN 1359-7345

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Abstract

Reaction of chiral ester linked diynes with chlorotris(triphenylphosphine)cobalt(I) and sodium cyclopentadienide gave (?5-cyclopentadienyl)(triphenylphosphine) cobaltacyclopentadiene complexes as single chiral-at-metal diastereoisomers, including a non-racemic example synthesised in three steps from (S)-3-butyn-2-ol.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
University of East Anglia > Faculty of Science > Research Groups > Synthetic Chemistry
Related URLs:
Depositing User: Rachel Smith
Date Deposited: 12 Apr 2013 21:22
Last Modified: 25 Jul 2018 03:22
URI: https://ueaeprints.uea.ac.uk/id/eprint/42016
DOI: 10.1039/C2CC34837C

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