Novel biphenyl organocatalysts for iminium ion-catalyzed asymmetric epoxidation

Farah, Mohamed M., Bulman Page, Philip, Buckley, Benjamin R., Blacker, A. John and Elsegood, Mark R.J. (2013) Novel biphenyl organocatalysts for iminium ion-catalyzed asymmetric epoxidation. Tetrahedron, 69 (2). pp. 758-769.

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Abstract

Two novel chiral biphenyl iminium salts derived from l-acetonamine, containing electron-withdrawing 3,3'-substituents on the biphenyl unit, have been prepared and tested as asymmetric catalysts for epoxidation of prochiral alkenes. The results are compared with those achieved using the corresponding unsubstituted system.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
University of East Anglia > Faculty of Science > Research Groups > Synthetic Chemistry
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Depositing User: Rachel Smith
Date Deposited: 20 Mar 2013 15:10
Last Modified: 05 Sep 2018 12:30
URI: https://ueaeprints.uea.ac.uk/id/eprint/41960
DOI: 10.1016/j.tet.2012.10.076

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