A C-2-symmetric metallocene-pyrrolidinopyridine nucleophilic catalyst for asymmetric synthesis

Nguyen, H. V., Motevalli, M. and Richards, C. J. (2007) A C-2-symmetric metallocene-pyrrolidinopyridine nucleophilic catalyst for asymmetric synthesis. Synlett (5). pp. 725-728. ISSN 0936-5214

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Abstract

A C-2 -symmetric nucleophilic catalyst, (R,R)-3,5-diferrocenyl-4-(2',5'-dimethylpyrrolidino)pyridine, was synthesised in three steps from commercially available (S,S)-hexane-2,5-diol. Application to the kinetic resolution of secondary alcohols (0.5 mol% loading) resulted in selectivity factors (s) of up to 6.

Item Type: Article
Additional Information: Nguyen, Huy V. Motevalli, Majid Richards, Christopher J.
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 21 Feb 2012 10:46
Last Modified: 11 Apr 2019 15:35
URI: https://ueaeprints.uea.ac.uk/id/eprint/37282
DOI: 10.1055/s-2007-970764

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